You can't simply state which weapon is the best, it depends on situation, and level really. Here are some good ones though:
Knives:
Devourer sting,
Icicle,
Poisonous bluesteel dagger,
Stileto
Nanocarbon scalpel
Magma shortsword
Deathclaw
Offhand:
Dirk of the gambler
Dirk of betrayal
Flaming Dirk
Cursed fang
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